Quantum Mechanics
Schrodinger equation
Quantum Mechanics
Propagators : Pg
Quantum Simple Harmonic Oscillator QSHO
Quantum Mechanics
Simulation With GNU Octave
© The scientific sentence. 2010
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| Hilbert space
The most part in the study of Quamtum Physics is purely
algebraic manipulations.
1. Definitions
Hilbert space is a vector space, that
is a space in wich we operate with vectors of one, or
two or three or more dimentions. It is different from other
vector spaces by its properties.
In Physics, Hilbert space is used mainly in quantum Mechanics
by the means of operators acting on wave functions.
Properties of Hilbert space:
Hilbert space H works over the C set (complex numbers). It is
then a complex vector space.
On this space, we define an inner product < , > as follows:
- < f, g > = < g, f>* (* denotes the complex conjugate)
- < α f + βg , h > = α < f , h > + β < g , h >
- If f ≠ 0 then < f, f > > 0
This space is complete with the definition of the norm:
- ||f|| = < f, f > 1/2
f, g, and h in H and α and β in C.
2. The 1-Operator
We will use the Dirac notation by calling <ψ| a bra,
and |ψ> a ket, so: <ψ|ψ> is a braket.
Let's assume {|φn >} a set of linear independent vectors in
the Hibert space H; and this set is an orthogonal vectors set,
that is < φm|φn >= δnm. This set constitutes the basis
in the Hilebert space. Therefore, we can expand every arbitrary
vector in H according this basis as:
|ψ> = Σ an |φn> n from 1 to ∞
Thus:
<φm | ψ > = Σ an <φm |φn> n from 1 to ∞
= an δnm = am
Hence, each vector can be represented as:
|ψ> = Σ <φn | ψ > |φn >
n from 1 to ∞
Or:
|ψ> = Σ |φn ><φn | ψ > n from 1 to ∞
From this relation we get:
Σ |φn><φn| = 1
n from 1 to ∞
Called the 1-Operator
||ψ||2 = <ψ|ψ> = <ψ|Σ |φn ><φn | ψ > =
Σ <ψ|φn ><φn | ψ > = Σ <φn|ψ>* <φn | ψ > =
Σ |<φn|ψ>|2
n from 1 to ∞
3. Linear Oprators in Hilbert space
3.1. Action of an operator:
An operator A in Hilbert space acts on a
vector |ψ> as follows:
A|ψ> = |A ψ> = |ψ'>
A|ψ> = |A ψ> = |ψ'>
3.2. Adjoint operator:
A+ is the adjoint of A if:
<φ|A|ψ> = <A+φ|ψ>
<φ|A|ψ> = <A+φ|ψ>
A+ is the adjoint of A
3.3 Hermitian operator:
The operator A is hermitian if:
<φ|A|ψ> = <Aφ|ψ>
<φ|A|ψ> = <Aφ|ψ>
A is hermitian
4. Cauchy-Schwarz inequality) |<x,y>| <= ||x||.||y||
In a real vector space, then for any real λ, we have:
0 <= <x + λy, x+ λy> = <x,x +λy> +λ <y,x + λy> =
<x,x> + 2λ<x,y> + λ2<y,y> = ||x||2 + 2λ<<x,y> + λ2||y||2 .
Minimizing ( deriving with respect to λ), we get:
2<x,y> + 2λ||y||2 = 0, that is:
λ = - <x,y>/||y||2.
Substituting this value in the inequality, yields:
0 <= ||x||2 - 2(<x,y>/||y||2)<x,y> + (<x,y>2/||y||4)||y||2
0 <= ||x||2 - 2(<x,y>2/||y||2 + <x,y>2/||y||2
0 <= ||x||2 - <x,y>2/||y||2
<x,y>2 <= ||x||2||y||2
<x,y> <= ||x||||y||
<x,y> <= ||x||.||y||
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